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Discussion of precise time and frequency measurement

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Lifetime of Cesium tube

B
bill
Fri, May 13, 2005 1:29 AM

Brooke Clarke wrote:

Hi Bill:

I wouldn't trade in my Cs just yet.  Have a look at the performance:
http://tf.nist.gov/ofm/smallclock/Performance.htm

73,

Brooke Clarke, N6GCE

OK so the design needs a "little" work  Still, it seems to be my only hope
of buying a "new" Cesium.

However by the time they get the performance up I won't want one anyway :-)
Oh, and I don't have a Cesium now, I have to make due with a Crystal
(from Austron)
adjusted to keep up with GPS. I keep my Austron at better than 10e-9.
Not very accurate
as standards go. I can do better but I don't need to.

Bill K7NOM

Brooke Clarke wrote: > Hi Bill: > > I wouldn't trade in my Cs just yet. Have a look at the performance: > http://tf.nist.gov/ofm/smallclock/Performance.htm > > 73, > > Brooke Clarke, N6GCE OK so the design needs a "little" work Still, it seems to be my only hope of buying a "new" Cesium. However by the time they get the performance up I won't want one anyway :-) Oh, and I don't have a Cesium now, I have to make due with a Crystal (from Austron) adjusted to keep up with GPS. I keep my Austron at better than 10e-9. Not very accurate as standards go. I can do better but I don't need to. Bill K7NOM
TV
Tom Van Baak
Fri, May 13, 2005 1:46 AM

Molecule: A unit of matter, the smallest portion of an element or
compound that retains chemical identity with the substance in mass.

I don't know about an official chemistry definition
but in the context of timekeeping and clocks, you
will see the term molecule used only in the case
of ammonia; the first atomic clock in 1949; where
it is sometimes, correctly so, called a "molecular
clock".

The rest of the clocks -- the ones based on hydrogen,
cesium, rubidium, etc. -- are called atomic clocks
and the happy bits of matter that fly around are called
atoms, by both technical literature and popular press.

A good example of the proper use of the terms
molecular and atomic in the context of clocks is:
http://tycho.usno.navy.mil/cesium.html

/tvb

> Molecule: A unit of matter, the smallest portion of an *element* or > compound that retains chemical identity with the substance in mass. I don't know about an official chemistry definition but in the context of timekeeping and clocks, you will see the term molecule used only in the case of ammonia; the first atomic clock in 1949; where it is sometimes, correctly so, called a "molecular clock". The rest of the clocks -- the ones based on hydrogen, cesium, rubidium, etc. -- are called atomic clocks and the happy bits of matter that fly around are called atoms, by both technical literature and popular press. A good example of the proper use of the terms molecular and atomic in the context of clocks is: http://tycho.usno.navy.mil/cesium.html /tvb
PK
Poul-Henning Kamp
Fri, May 13, 2005 2:11 AM

It's really very easy:  If it were a molecule, the Cesium clock
would not work because the outher electron would could not be
interogated relative to the kernel.

It would not work with a neutral atom however, because the
the state selector magnet needs the charge to work against.

At least that's how I remember it.

--
Poul-Henning Kamp      | UNIX since Zilog Zeus 3.20
phk@FreeBSD.ORG        | TCP/IP since RFC 956
FreeBSD committer      | BSD since 4.3-tahoe
Never attribute to malice what can adequately be explained by incompetence.

It's really very easy: If it were a molecule, the Cesium clock would not work because the outher electron would could not be interogated relative to the kernel. It would not work with a neutral atom however, because the the state selector magnet needs the charge to work against. At least that's how I remember it. -- Poul-Henning Kamp | UNIX since Zilog Zeus 3.20 phk@FreeBSD.ORG | TCP/IP since RFC 956 FreeBSD committer | BSD since 4.3-tahoe Never attribute to malice what can adequately be explained by incompetence.
CH
Chuck Harris
Fri, May 13, 2005 2:26 AM

Hi Poul-Hemming,

One neutral Cesium atom is a molecule by definition because it
is the smallest possible unit that contains all of the properties
of Cesium metal in bulk.

That is the definition we worked with in the Chemistry I took in
college.  I have never heard a different definition.

Since a single neutral atom of Cesium is a molecule, I don't understand
your reference about the outer electron, unless you are imagining a
molecule of Cesium and some other element (eg, Cesium oxide).

As to the C-beam not working with a neutral Cesium atom, I have already
been hammered by Rick Karlquest for saying that the C-Beam uses Cesium
ions.  He apparently knows otherwise.  Prior to his letter, I thought
as you state.  Now I am just confused.

-Chuck

Poul-Henning Kamp wrote:

It's really very easy:  If it were a molecule, the Cesium clock
would not work because the outher electron would could not be
interogated relative to the kernel.

It would not work with a neutral atom however, because the
the state selector magnet needs the charge to work against.

At least that's how I remember it.

Hi Poul-Hemming, One neutral Cesium atom is a molecule by definition because it is the smallest possible unit that contains all of the properties of Cesium metal in bulk. That is the definition we worked with in the Chemistry I took in college. I have never heard a different definition. Since a single neutral atom of Cesium is a molecule, I don't understand your reference about the outer electron, unless you are imagining a molecule of Cesium and some other element (eg, Cesium oxide). As to the C-beam not working with a neutral Cesium atom, I have already been hammered by Rick Karlquest for saying that the C-Beam uses Cesium ions. He apparently knows otherwise. Prior to his letter, I thought as you state. Now I am just confused. -Chuck Poul-Henning Kamp wrote: > It's really very easy: If it were a molecule, the Cesium clock > would not work because the outher electron would could not be > interogated relative to the kernel. > > It would not work with a neutral atom however, because the > the state selector magnet needs the charge to work against. > > At least that's how I remember it. >
PK
Poul-Henning Kamp
Fri, May 13, 2005 2:30 AM

In message 4284104E.9080204@erols.com, Chuck Harris writes:

Hi Poul-Hemming,

One neutral Cesium atom is a molecule by definition because it
is the smallest possible unit that contains all of the properties
of Cesium metal in bulk.

I was brought up to belive that it took at least two atoms to make
a molecule.

--
Poul-Henning Kamp      | UNIX since Zilog Zeus 3.20
phk@FreeBSD.ORG        | TCP/IP since RFC 956
FreeBSD committer      | BSD since 4.3-tahoe
Never attribute to malice what can adequately be explained by incompetence.

In message <4284104E.9080204@erols.com>, Chuck Harris writes: >Hi Poul-Hemming, > >One neutral Cesium atom is a molecule by definition because it >is the smallest possible unit that contains all of the properties >of Cesium metal in bulk. I was brought up to belive that it took at least two atoms to make a molecule. -- Poul-Henning Kamp | UNIX since Zilog Zeus 3.20 phk@FreeBSD.ORG | TCP/IP since RFC 956 FreeBSD committer | BSD since 4.3-tahoe Never attribute to malice what can adequately be explained by incompetence.
CH
Chuck Harris
Fri, May 13, 2005 3:40 AM

Poul-Henning Kamp wrote:

In message 4284104E.9080204@erols.com, Chuck Harris writes:

Hi Poul-Hemming,

One neutral Cesium atom is a molecule by definition because it
is the smallest possible unit that contains all of the properties
of Cesium metal in bulk.

I was brought up to belive that it took at least two atoms to make
a molecule.

Then you cannot have a molecule of iron, gold, silver...  In any case,
it is just mincing words.  I don't believe that anyone, myself included,
believed that when I said a Cesium molecule that I was discussing anything
other than the metal Cesium.

If the C-beam standard had been invented in an era other than the "atomic age",
it probably would have been called something other than an atomic standard.

-Chuck

Poul-Henning Kamp wrote: > In message <4284104E.9080204@erols.com>, Chuck Harris writes: > >>Hi Poul-Hemming, >> >>One neutral Cesium atom is a molecule by definition because it >>is the smallest possible unit that contains all of the properties >>of Cesium metal in bulk. > > > I was brought up to belive that it took at least two atoms to make > a molecule. Then you cannot have a molecule of iron, gold, silver... In any case, it is just mincing words. I don't believe that anyone, myself included, believed that when I said a Cesium molecule that I was discussing anything other than the metal Cesium. If the C-beam standard had been invented in an era other than the "atomic age", it probably would have been called something other than an atomic standard. -Chuck
BH
Bill Hawkins
Fri, May 13, 2005 4:25 AM

"This is an argument."

"No, it's not!"

Monty Python

"This is an argument." "No, it's not!" Monty Python
MW
M. Warner Losh
Fri, May 13, 2005 4:43 AM

In message: 009401c55773$d4024020$0500a8c0@darius.domain.actdsltmp
"Bill Hawkins" bill@iaxs.net writes:
: "This is an argument."
:
: "No, it's not!"

"No It isn't." I believe is the quote.

In the circles I run, usually molecules are referred to when talking
about chemical interaction, and atoms when talking about sub-atomic
interactions (like transitions between hyperfine states :-).  However,
other circles likley have different criteria to determine what terms
to use.  However, this argument has become less interesting than the
HP part number nuance argument that has been declared persona
non-grata.  Maybe people here can do the math... :-)

Warner

In message: <009401c55773$d4024020$0500a8c0@darius.domain.actdsltmp> "Bill Hawkins" <bill@iaxs.net> writes: : "This is an argument." : : "No, it's not!" "No It isn't." I believe is the quote. In the circles I run, usually molecules are referred to when talking about chemical interaction, and atoms when talking about sub-atomic interactions (like transitions between hyperfine states :-). However, other circles likley have different criteria to determine what terms to use. However, this argument has become less interesting than the HP part number nuance argument that has been declared persona non-grata. Maybe people here can do the math... :-) Warner