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OCXO housings - Why copper and not iron/steel?

BK
Bob kb8tq
Sat, Oct 31, 2020 12:05 AM

Hi

Gradients are a really big deal in an OCXO. Thermal mass works against
you if you are after quick warmup ….

Bob

On Oct 30, 2020, at 6:23 PM, Attila Kinali attila@kinali.ch wrote:

On Fri, 30 Oct 2020 17:58:24 -0400
Bob kb8tq kb8tq@n1k.org wrote:

Simple answer: conductivity. You don’t get much heat capacity either way.

Ah.. so it is more important to have less temperature gradients
than having high capacity?

		Attila Kinali

--
<JaberWorky> The bad part of Zurich is where the degenerates
throw DARK chocolate at you.


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Hi Gradients are a really big deal in an OCXO. Thermal mass works against you if you are after quick warmup …. Bob > On Oct 30, 2020, at 6:23 PM, Attila Kinali <attila@kinali.ch> wrote: > > On Fri, 30 Oct 2020 17:58:24 -0400 > Bob kb8tq <kb8tq@n1k.org> wrote: > >> Simple answer: conductivity. You don’t get much heat capacity either way. > > Ah.. so it is more important to have less temperature gradients > than having high capacity? > > Attila Kinali > > -- > <JaberWorky> The bad part of Zurich is where the degenerates > throw DARK chocolate at you. > > _______________________________________________ > time-nuts mailing list -- time-nuts@lists.febo.com > To unsubscribe, go to http://lists.febo.com/mailman/listinfo/time-nuts_lists.febo.com > and follow the instructions there.
R(
Richard (Rick) Karlquist
Sat, Oct 31, 2020 2:23 AM

On 10/30/2020 5:05 PM, Bob kb8tq wrote:

Hi

Gradients are a really big deal in an OCXO. Thermal mass works against
you if you are after quick warmup ….

Bob

I'll take this opportunity to plug my 1997 FCS paper:
"The Theory of Zero Gradient Ovens" explaining how
we got thermal gain over 1 million.  You better
believe gradients are a really big deal.

Rick N6RK

On 10/30/2020 5:05 PM, Bob kb8tq wrote: > Hi > > Gradients are a really big deal in an OCXO. Thermal mass works against > you if you are after quick warmup …. > > Bob > I'll take this opportunity to plug my 1997 FCS paper: "The Theory of Zero Gradient Ovens" explaining how we got thermal gain over 1 million. You better believe gradients are a really big deal. Rick N6RK
BG
Bruce Griffiths
Sat, Oct 31, 2020 2:50 AM

Not true
The Wiedemann-Franz gives the ratio of the thermal conductivity to electrical conductivity of a metal:
( pi^2 / 3 ) * ( (k/e)^2 ) * T

Bruce

On 31 October 2020 at 12:49 "Dr. David Kirkby" drkirkby@kirkbymicrowave.co.uk wrote:

On Fri, 30 Oct 2020 at 22:17, Luiz Alberto Saba las@intercat.com.br wrote:

My bad... copper is the second, losing only to silver, as a thermal
conductor.

I think you are mistaken.  Copper is second to silver for electrical
conductivity, but I doubt that is so for thermal conductivity. I think
diamond, which is a form of carbon, is the best thermal conductor, and
around 5x better than copper.

Dave

--
Dr. David Kirkby,
Kirkby Microwave Ltd,
drkirkby@kirkbymicrowave.co.uk
https://www.kirkbymicrowave.co.uk/
Telephone 01621-680100./ +44 1621 680100

Registered in England & Wales, company number 08914892.
Registered office:
Stokes Hall Lodge, Burnham Rd, Althorne, Chelmsford, Essex, CM3 6DT, United
Kingdom


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Not true The Wiedemann-Franz gives the ratio of the thermal conductivity to electrical conductivity of a metal: ( pi^2 / 3 ) * ( (k/e)^2 ) * T Bruce > On 31 October 2020 at 12:49 "Dr. David Kirkby" <drkirkby@kirkbymicrowave.co.uk> wrote: > > > On Fri, 30 Oct 2020 at 22:17, Luiz Alberto Saba <las@intercat.com.br> wrote: > > > My bad... copper is the second, losing only to silver, as a thermal > > conductor. > > > > I think you are mistaken. Copper is second to silver for *electrical* > conductivity, but I doubt that is so for thermal conductivity. I think > diamond, which is a form of carbon, is the best thermal conductor, and > around 5x better than copper. > > Dave > > -- > Dr. David Kirkby, > Kirkby Microwave Ltd, > drkirkby@kirkbymicrowave.co.uk > https://www.kirkbymicrowave.co.uk/ > Telephone 01621-680100./ +44 1621 680100 > > Registered in England & Wales, company number 08914892. > Registered office: > Stokes Hall Lodge, Burnham Rd, Althorne, Chelmsford, Essex, CM3 6DT, United > Kingdom > _______________________________________________ > time-nuts mailing list -- time-nuts@lists.febo.com > To unsubscribe, go to http://lists.febo.com/mailman/listinfo/time-nuts_lists.febo.com > and follow the instructions there.
TP
Tobias Pluess
Sat, Oct 31, 2020 11:47 AM

Also an interesting material when high thermal conductivity is considered
is boron nitride. It is around  five times better than copper, comparable
to diamond and can be sintered to a ceramic material.
Of course the Wiedemann-Franz-Lorenz law doesn't apply here as it is a very
good electrical insulator.
A boron nitride OCXO would indeed be interesting! :-)

I use certain kinds of boron nitride at work to increase the the thermal
conductivity of some plastic materials.

Tobias

On Sat., 31 Oct. 2020, 03:57 Bruce Griffiths, bruce.griffiths@xtra.co.nz
wrote:

Not true
The Wiedemann-Franz gives the ratio of the thermal conductivity to
electrical conductivity of a metal:
( pi^2 / 3 ) * ( (k/e)^2 ) * T

Bruce

On 31 October 2020 at 12:49 "Dr. David Kirkby" <

On Fri, 30 Oct 2020 at 22:17, Luiz Alberto Saba las@intercat.com.br

wrote:

My bad... copper is the second, losing only to silver, as a thermal
conductor.

I think you are mistaken.  Copper is second to silver for electrical
conductivity, but I doubt that is so for thermal conductivity. I think
diamond, which is a form of carbon, is the best thermal conductor, and
around 5x better than copper.

Dave

--
Dr. David Kirkby,
Kirkby Microwave Ltd,
drkirkby@kirkbymicrowave.co.uk
https://www.kirkbymicrowave.co.uk/
Telephone 01621-680100./ +44 1621 680100

Registered in England & Wales, company number 08914892.
Registered office:
Stokes Hall Lodge, Burnham Rd, Althorne, Chelmsford, Essex, CM3 6DT,

United

Kingdom


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Also an interesting material when high thermal conductivity is considered is boron nitride. It is around five times better than copper, comparable to diamond and can be sintered to a ceramic material. Of course the Wiedemann-Franz-Lorenz law doesn't apply here as it is a very good electrical insulator. A boron nitride OCXO would indeed be interesting! :-) I use certain kinds of boron nitride at work to increase the the thermal conductivity of some plastic materials. Tobias On Sat., 31 Oct. 2020, 03:57 Bruce Griffiths, <bruce.griffiths@xtra.co.nz> wrote: > Not true > The Wiedemann-Franz gives the ratio of the thermal conductivity to > electrical conductivity of a metal: > ( pi^2 / 3 ) * ( (k/e)^2 ) * T > > Bruce > > On 31 October 2020 at 12:49 "Dr. David Kirkby" < > drkirkby@kirkbymicrowave.co.uk> wrote: > > > > > > On Fri, 30 Oct 2020 at 22:17, Luiz Alberto Saba <las@intercat.com.br> > wrote: > > > > > My bad... copper is the second, losing only to silver, as a thermal > > > conductor. > > > > > > > I think you are mistaken. Copper is second to silver for *electrical* > > conductivity, but I doubt that is so for thermal conductivity. I think > > diamond, which is a form of carbon, is the best thermal conductor, and > > around 5x better than copper. > > > > Dave > > > > -- > > Dr. David Kirkby, > > Kirkby Microwave Ltd, > > drkirkby@kirkbymicrowave.co.uk > > https://www.kirkbymicrowave.co.uk/ > > Telephone 01621-680100./ +44 1621 680100 > > > > Registered in England & Wales, company number 08914892. > > Registered office: > > Stokes Hall Lodge, Burnham Rd, Althorne, Chelmsford, Essex, CM3 6DT, > United > > Kingdom > > _______________________________________________ > > time-nuts mailing list -- time-nuts@lists.febo.com > > To unsubscribe, go to > http://lists.febo.com/mailman/listinfo/time-nuts_lists.febo.com > > and follow the instructions there. > > _______________________________________________ > time-nuts mailing list -- time-nuts@lists.febo.com > To unsubscribe, go to > http://lists.febo.com/mailman/listinfo/time-nuts_lists.febo.com > and follow the instructions there. >
LA
Luiz Alberto Saba
Sat, Oct 31, 2020 12:10 PM

Em 30 de out. de 2020, à(s) 23:57, Bruce Griffiths bruce.griffiths@xtra.co.nz escreveu:

Not true
The Wiedemann-Franz gives the ratio of the thermal conductivity to electrical conductivity of a metal:
( pi^2 / 3 ) * ( (k/e)^2 ) * T

Bruce

On 31 October 2020 at 12:49 "Dr. David Kirkby" drkirkby@kirkbymicrowave.co.uk wrote:

On Fri, 30 Oct 2020 at 22:17, Luiz Alberto Saba las@intercat.com.br wrote:

My bad... copper is the second, losing only to silver, as a thermal
conductor.

I think you are mistaken.  Copper is second to silver for electrical
conductivity, but I doubt that is so for thermal conductivity. I think
diamond, which is a form of carbon, is the best thermal conductor, and
around 5x better than copper.

Dave

--
Dr. David Kirkby,
Kirkby Microwave Ltd,
drkirkby@kirkbymicrowave.co.uk
https://www.kirkbymicrowave.co.uk/
Telephone 01621-680100./ +44 1621 680100

Registered in England & Wales, company number 08914892.
Registered office:
Stokes Hall Lodge, Burnham Rd, Althorne, Chelmsford, Essex, CM3 6DT, United
Kingdom


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Interesting list https://thermtest.com/thermal-resources/top-10-thermally-conductive-materials Enviado do meu iPhone > Em 30 de out. de 2020, à(s) 23:57, Bruce Griffiths <bruce.griffiths@xtra.co.nz> escreveu: > > Not true > The Wiedemann-Franz gives the ratio of the thermal conductivity to electrical conductivity of a metal: > ( pi^2 / 3 ) * ( (k/e)^2 ) * T > > Bruce >> On 31 October 2020 at 12:49 "Dr. David Kirkby" <drkirkby@kirkbymicrowave.co.uk> wrote: >> >> >>> On Fri, 30 Oct 2020 at 22:17, Luiz Alberto Saba <las@intercat.com.br> wrote: >>> >>> My bad... copper is the second, losing only to silver, as a thermal >>> conductor. >>> >> >> I think you are mistaken. Copper is second to silver for *electrical* >> conductivity, but I doubt that is so for thermal conductivity. I think >> diamond, which is a form of carbon, is the best thermal conductor, and >> around 5x better than copper. >> >> Dave >> >> -- >> Dr. David Kirkby, >> Kirkby Microwave Ltd, >> drkirkby@kirkbymicrowave.co.uk >> https://www.kirkbymicrowave.co.uk/ >> Telephone 01621-680100./ +44 1621 680100 >> >> Registered in England & Wales, company number 08914892. >> Registered office: >> Stokes Hall Lodge, Burnham Rd, Althorne, Chelmsford, Essex, CM3 6DT, United >> Kingdom >> _______________________________________________ >> time-nuts mailing list -- time-nuts@lists.febo.com >> To unsubscribe, go to http://lists.febo.com/mailman/listinfo/time-nuts_lists.febo.com >> and follow the instructions there. > > _______________________________________________ > time-nuts mailing list -- time-nuts@lists.febo.com > To unsubscribe, go to http://lists.febo.com/mailman/listinfo/time-nuts_lists.febo.com > and follow the instructions there.
BN
Bernd Neubig
Sun, Nov 1, 2020 10:20 AM

-----Tobias wrote-----

Also an interesting material when high thermal conductivity is considered

is boron nitride. It is around  five times better than copper, comparable to
diamond and can be sintered to a ceramic material.

Of course the Wiedemann-Franz-Lorenz law doesn't apply here as it is a very

good electrical insulator.

A boron nitride OCXO would indeed be interesting! :-)

About 30 years ago, in my previous job as head of TeleQuarz oscillator
division (now Vectron->...Microchip), we had used AlN hybrid substrates
replacing the FR4 PCB in OCXO. We had built up a complete hybrid
manufacturing line for that. Aluminum Nitride has an extremely high thermal
conductivity while being an isolator. The thermal performance was excellent.
However it was nearly impossible to solder on it manually (e.g. to change
components for fine tuning purposes) because the solder literally was
freezing on the substrate and even a special soldering iron with temperature
regulation directly in thee tip (Metcal) was not able to deliver sufficient
heat fast enough. After a few years we stopped this line.

Have a nice Sunday.
Bernd

-----Tobias wrote----- >Also an interesting material when high thermal conductivity is considered is boron nitride. It is around five times better than copper, comparable to diamond and can be sintered to a ceramic material. >Of course the Wiedemann-Franz-Lorenz law doesn't apply here as it is a very good electrical insulator. >A boron nitride OCXO would indeed be interesting! :-) About 30 years ago, in my previous job as head of TeleQuarz oscillator division (now Vectron->...Microchip), we had used AlN hybrid substrates replacing the FR4 PCB in OCXO. We had built up a complete hybrid manufacturing line for that. Aluminum Nitride has an extremely high thermal conductivity while being an isolator. The thermal performance was excellent. However it was nearly impossible to solder on it manually (e.g. to change components for fine tuning purposes) because the solder literally was freezing on the substrate and even a special soldering iron with temperature regulation directly in thee tip (Metcal) was not able to deliver sufficient heat fast enough. After a few years we stopped this line. Have a nice Sunday. Bernd
BK
Bob kb8tq
Sun, Nov 1, 2020 1:33 PM

Hi

….. and of course, there was an OCXO that used a beryllium oxide substrate
in pretty much the same way (inner oven in a double oven). Same basic issues
and not exactly cost effective.

The alumina substrate lives on in a number of miniature oven designs.

Bob

On Nov 1, 2020, at 5:20 AM, Bernd Neubig BNeubig@t-online.de wrote:

-----Tobias wrote-----

Also an interesting material when high thermal conductivity is considered

is boron nitride. It is around  five times better than copper, comparable to
diamond and can be sintered to a ceramic material.

Of course the Wiedemann-Franz-Lorenz law doesn't apply here as it is a very

good electrical insulator.

A boron nitride OCXO would indeed be interesting! :-)

About 30 years ago, in my previous job as head of TeleQuarz oscillator
division (now Vectron->...Microchip), we had used AlN hybrid substrates
replacing the FR4 PCB in OCXO. We had built up a complete hybrid
manufacturing line for that. Aluminum Nitride has an extremely high thermal
conductivity while being an isolator. The thermal performance was excellent.
However it was nearly impossible to solder on it manually (e.g. to change
components for fine tuning purposes) because the solder literally was
freezing on the substrate and even a special soldering iron with temperature
regulation directly in thee tip (Metcal) was not able to deliver sufficient
heat fast enough. After a few years we stopped this line.

Have a nice Sunday.
Bernd


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Hi ….. and of course, there was an OCXO that used a beryllium oxide substrate in pretty much the same way (inner oven in a double oven). Same basic issues and not exactly cost effective. The alumina substrate lives on in a number of miniature oven designs. Bob > On Nov 1, 2020, at 5:20 AM, Bernd Neubig <BNeubig@t-online.de> wrote: > > > > -----Tobias wrote----- >> Also an interesting material when high thermal conductivity is considered > is boron nitride. It is around five times better than copper, comparable to > diamond and can be sintered to a ceramic material. >> Of course the Wiedemann-Franz-Lorenz law doesn't apply here as it is a very > good electrical insulator. >> A boron nitride OCXO would indeed be interesting! :-) > > About 30 years ago, in my previous job as head of TeleQuarz oscillator > division (now Vectron->...Microchip), we had used AlN hybrid substrates > replacing the FR4 PCB in OCXO. We had built up a complete hybrid > manufacturing line for that. Aluminum Nitride has an extremely high thermal > conductivity while being an isolator. The thermal performance was excellent. > However it was nearly impossible to solder on it manually (e.g. to change > components for fine tuning purposes) because the solder literally was > freezing on the substrate and even a special soldering iron with temperature > regulation directly in thee tip (Metcal) was not able to deliver sufficient > heat fast enough. After a few years we stopped this line. > > Have a nice Sunday. > Bernd > > > > _______________________________________________ > time-nuts mailing list -- time-nuts@lists.febo.com > To unsubscribe, go to http://lists.febo.com/mailman/listinfo/time-nuts_lists.febo.com > and follow the instructions there.